Effect of compression wood on leaching and fixation of CCA-C treated red pine

Abstract

In this study, we investigated the effect of compression wood on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait.) and the rate of fixation of hexavalent chromium in the wood. Wood blocks from red pine, some containing compression wood and some with normal wood, were treated with a 1.0% CCA-C solution and then allowed to fix at 23 degreesC +/- 2 (74 degreesF +/- 4) for 0, 6, 24, 48, 96, 192, and 336 h. After each fixation period, sets of blocks removed from the conditioning room were subjected to 336 h of leaching. The percentage of hexavalent chromium reduced to the trivalent state was determined for solution pressed from matched sets of blocks. The blocks containing compression wood released significantly less chromium and copper elements. For chromium, the biggest effect was seen after the 192- and 336-h fixation periods. in the normal wood blocks fixed for 336 h, the average chromium release rate after 6 h of leaching was almost five times greater than that of the compression wood blocks. Copper and arsenic release was also affected by compression wood, but for these two elements, the effect diminished during the later stages of fixation. A higher percentage of hexavalent chromium was reduced to trivalent chromium in compression wood compared with that in normal wood after most fixation periods, and this difference was significant after 0, 48, 96, and 192 h.