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The two-dimensional coordination polymer poly[[bis(3-methylpyridine)cadmium(II)]-tetra-mu-cyano-nickel(II)]

Author
Utlu, G
Ozbey, S
Gokce, AG
Akyuz, S
Aygun, M
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Abstract
The title complex, [CdNi(CN)(4)(C6H7N)(2)](n), adopts a slightly distorted octahedral geometry around the Cd centre. Four cyanide N atoms occupy the equatorial coordination sites around the Cd centre. The structure consists of corrugated and cyanide-bridged polymeric networks made up of tetracyanonickelate ions coordinated to cadmium, with the Ni ion coordinated by four cyanide ligands in a square-planar arrangement. The Cd and Ni atoms occupy special positions of 2/m site symmetry. The 3-methylpyridine group, except for two methyl H atoms, lies on a crystallographic mirror plane. The 3-methylpyridine molecules, bound to cadmium in trans positions, are located on both sides of the network. The bonding in the networks occurs because of a departure of the Ni-C-N-Cd sequence of atoms from linearity at the C and N atoms.
URI
http://hdl.handle.net/20.500.12627/8357
https://doi.org/10.1107/s0108270105000636
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Creative Commons Lisansı

İstanbul Üniversitesi Akademik Arşiv Sistemi (ilgili içerikte aksi belirtilmediği sürece) Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.

DSpace software copyright © 2002-2016  DuraSpace
Contact Us | Send Feedback
Theme by 
Atmire NV