Reactions of pentachloro-2-nitrobutadiene with some aliphatic and heterocyclic thiols and a crystallographic study

Abstract

In this study, S-, S,S- and S,O-substituted novel nitrodiene compounds were synthesized. Cyclization products were formed when difunctional nucleophiles were used. The stereoisomerism of a heterocyclic nitrodiene is discussed with the help of XRD studies. The structures of all compounds were characterized by spectroscopic methods (FT-IR, H-1 NMR, C-13 NMR, F-19 NMR, MS) and microanalysis.