The Synthesis of Novel S-, S,S-, S,S,S-, S,O-, N,S-Substituted Halogenobuta-1,3-dienes

Abstract

In this work, thiosubstituted nitrodiene compounds (3, 4a, 5a, b, 6c, 7a, 7c, 9) we re obtained from the reactions of some thiols with 2-nitropentachloro-1,3-butadiene. N,S-Substituted nitrodiene compounds (11a-g, 13, 15) we re obtained from 2-nitropentachloro-1,3-butadiene and some amines (morpholine and piperazine derivatives). The compound 4a was crystallized in the triclinic crystal system (space group P-1) with the unit cell parameters a = 6.6525(7) angstrom, b = 10.7906(5) angstrom, c = 10.8339(4) angstrom, alpha = 72.57(3)degrees, beta = 84.23(4)degrees, gamma = 75.81(3)degrees, V = 719.03(9) angstrom(3), Z = 2. The no vel compounds were characterized by elemental analysis, UV-VIS, FT-IR, H-1-NMR, NMR (C-13 or APT) and mass spectros copy.