The Synthesis and Characterization of Some Novel Thioethers: Thio-Subsituted [3]Cumulenes,-1-Buten-3-ynes and Buta-1,3-dienes

Abstract

In this study, some novel thiosubstituted butenyne (3a-d, 7b, 15b), butadiene (4a-b, 4d, 5a, 5c, 6b, 8e, 9c, 10b, 16b, 18e) and [3]cumulene (11a-b with isomer 3a-b, 12a with isomer 13a, 14b, 17e) compounds were synthesized from the reaction of 2H-pentachloro- 1,3-butadiene with thiols. The new compounds were characterized by elemental analysis, mass spectrometry, UV-vis, IR, H-1 NMR, NMR (C-13 or APT) spectroscopy.