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dc.contributor.authorGemici, Aysegul
dc.contributor.authorKirbaslar, S. Ismail
dc.contributor.authorUslu, Hasan
dc.date.accessioned2021-03-04T19:36:38Z
dc.date.available2021-03-04T19:36:38Z
dc.date.issued2015
dc.identifier.citationGemici A., Uslu H., Kirbaslar S. I. , "Extractability of Fumaric Acid by Tributyl Amine (TBA) in Ketones and Alcohols", JOURNAL OF CHEMICAL AND ENGINEERING DATA, cilt.60, ss.2717-2720, 2015
dc.identifier.issn0021-9568
dc.identifier.othervv_1032021
dc.identifier.otherav_90921003-ef55-4e63-96fb-d1ce6118ec7c
dc.identifier.urihttp://hdl.handle.net/20.500.12627/97573
dc.identifier.urihttps://doi.org/10.1021/acs.jced.5b00398
dc.description.abstractFumaric acid extraction from aqueous media by tributyl amine (TBA), which is an aliphatic amine, was studied at 298 K. Ketones (methyl isobutyl ketone (MIBK), heptan-2-one, octan-2-one) and alcohols (isoamyl alcohol, octan-1-ol, decan-1-ol) were selected as the diluent for dissolving TBA. Distribution ratio (K-D), loading ratio (T), and extraction degree (D-E) were calculated from experimental results. 96% efficiency was reached with isoamyl alcohol at 2.08 mol.kg(-1) of TBA concentration. Futher, the linear solvation energy relationship (LSER) modeling cooperated with Hidebrand-Hansen solubility parameters was used for prediction KD of alcoholic diluents. The LSER model gave closeness prediction to experimental data.
dc.language.isoeng
dc.subjectKimya Mühendisliği ve Teknolojisi
dc.subjectTERMODİNAMİK
dc.subjectMühendislik
dc.subjectMühendislik, Bilişim ve Teknoloji (ENG)
dc.subjectTemel Bilimler
dc.subjectMühendislik ve Teknoloji
dc.subjectAlkoloidler
dc.subjectBiyokimya
dc.subjectMÜHENDİSLİK, KİMYASAL
dc.subjectTemel Bilimler (SCI)
dc.subjectKimya
dc.subjectKİMYA, MULTİDİSİPLİNER
dc.titleExtractability of Fumaric Acid by Tributyl Amine (TBA) in Ketones and Alcohols
dc.typeMakale
dc.relation.journalJOURNAL OF CHEMICAL AND ENGINEERING DATA
dc.contributor.departmentİstanbul Üniversitesi , ,
dc.identifier.volume60
dc.identifier.issue9
dc.identifier.startpage2717
dc.identifier.endpage2720
dc.contributor.firstauthorID48789


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