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Ionic conduction and molecular structure of molten FeCl3

dc.contributor.authorAkdeniz, Z
dc.contributor.authorTosi, MP
dc.date.accessioned2021-03-04T12:26:30Z
dc.date.available2021-03-04T12:26:30Z
dc.date.issued1998
dc.identifier.citationAkdeniz Z., Tosi M., "Ionic conduction and molecular structure of molten FeCl3", ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, cilt.53, sa.12, ss.960-962, 1998
dc.identifier.issn0932-0784
dc.identifier.otherav_774db0c1-f08c-49e7-93da-b170537ebe7b
dc.identifier.othervv_1032021
dc.identifier.urihttp://hdl.handle.net/20.500.12627/81904
dc.identifier.urihttps://doi.org/10.1515/zna-1998-1206
dc.description.abstractFormer experiments on molten FeCl3 have shown that, as for AlCl3, melting is accompanied by a transition from sixfold to essentially fourfold coordination. However, in contrast to AlCl3, the FeCl3 melt near freezing has an appreciable ionic conductivity. We propose a model for the structure of FeCl3 melt as consisting of closely packed Fe2Cl6 bitetrahedral molecules in equilibrium with (Fe2Cl5)(+) ana (Fe2Cl7)(-) ionised species.
dc.language.isoeng
dc.subjectFizik
dc.subjectTemel Bilimler
dc.subjectDisiplinlerarası Fizik ve İlgili Bilim ve Teknoloji Alanları
dc.subjectFizikokimya
dc.subjectFİZİK, MULTİDİSİPLİNER
dc.subjectTemel Bilimler (SCI)
dc.subjectKimya
dc.subjectKİMYA, FİZİKSEL
dc.titleIonic conduction and molecular structure of molten FeCl3
dc.typeMakale
dc.relation.journalZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
dc.contributor.department, ,
dc.identifier.volume53
dc.identifier.issue12
dc.identifier.startpage960
dc.identifier.endpage962
dc.contributor.firstauthorID121817


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