dc.contributor.author | Uelkueseven, Bahri | |
dc.contributor.author | Sahin, MUSA | |
dc.contributor.author | Bal-Demirci, Tulay | |
dc.contributor.author | Pozan-Soylu, Guelin | |
dc.date.accessioned | 2021-03-02T20:39:18Z | |
dc.date.available | 2021-03-02T20:39:18Z | |
dc.date.issued | 2009 | |
dc.identifier.citation | Sahin M., Bal-Demirci T., Pozan-Soylu G., Uelkueseven B., "Synthesis, characterization and thermal decomposition of dioxouranium(VI) complexes with N-1,N-4-diarylidene-S-propyl-thiosemicarbazone: Crystal structure of [UO2(L-I)(C4H9OH)]", INORGANICA CHIMICA ACTA, cilt.362, sa.7, ss.2407-2412, 2009 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.other | av_030c08af-0adb-4eab-817a-4393ef9cf790 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/7992 | |
dc.identifier.uri | https://doi.org/10.1016/j.ica.2008.10.036 | |
dc.description.abstract | Reactions of salicyl- and 3,5-dichlorosalicylaldehyde-S-propyl-thiosemicarbazones with salicyl- and 3,5-dichlorosalicylaldehyde in the presence of UO2(CH3COO)(2) in different alcohols yielded stable solid complexes corresponding to the general formula [UO2(L)ROH] (R: propyl-, butyl-, pentyl-, and octyl-). The complexes were characterized by means of elemental analysis, IR and H-1 NMR spectroscopies. The thermal stabilities of the alcohol solvated complexes were investigated in air and nitrogen atm., and determined their decomposition phases. In the crystal structure of the [UO2(L)(C4H9OH)], the U(VI) centre is seven-coordinated in a distorted pentagonal bipyramidal geometry involving O,O,N,N atoms of two phenolic and two imine groups and one oxygen atom of alcohol molecule in basal plane and two O atoms of dioxo group in apical positions. The title structure is stabilized by one intramolecular interaction of types C-H center dot center dot center dot Cl and by two intermolecular interactions of types O-H center dot center dot center dot O and C-H center dot center dot center dot pi (benzene) leading to the molecular chain along the [010] direction. (C) 2008 Elsevier B. V. All rights reserved. | |
dc.language.iso | eng | |
dc.subject | Temel Bilimler | |
dc.subject | İnorganik Kimya | |
dc.subject | Temel Bilimler (SCI) | |
dc.subject | Kimya | |
dc.subject | KİMYA, İNORGANİK VE NÜKLEER | |
dc.title | Synthesis, characterization and thermal decomposition of dioxouranium(VI) complexes with N-1,N-4-diarylidene-S-propyl-thiosemicarbazone: Crystal structure of [UO2(L-I)(C4H9OH)] | |
dc.type | Makale | |
dc.relation.journal | INORGANICA CHIMICA ACTA | |
dc.contributor.department | İstanbul Üniversitesi , , | |
dc.identifier.volume | 362 | |
dc.identifier.issue | 7 | |
dc.identifier.startpage | 2407 | |
dc.identifier.endpage | 2412 | |
dc.contributor.firstauthorID | 20715 | |