| dc.contributor.author | Kahruman, Cem | |
| dc.contributor.author | Kalpakli, Ahmet Orkun | |
| dc.contributor.author | Ilhan, Sedat | |
| dc.contributor.author | Yusufoglu, Ibrahim | |
| dc.date.accessioned | 2021-03-03T17:30:14Z | |
| dc.date.available | 2021-03-03T17:30:14Z | |
| dc.identifier.citation | Ilhan S., Kalpakli A. O. , Kahruman C., Yusufoglu I., "A KINETIC INVESTIGATION OF THE DISSOLUTION OF POWELLITE IN OXALIC ACID SOLUTIONS", T T Chen Honorary Symposium on Hydrometallurgy, Electrometallurgy and Materials Characterization held during the 141st TMS Annual Meeting and Exhibition, Florida, Amerika Birleşik Devletleri, 11 - 15 Mart 2012, ss.629-639 | |
| dc.identifier.other | vv_1032021 | |
| dc.identifier.other | av_4a11c44b-ec0c-467f-9d12-d4876b7fa46f | |
| dc.identifier.uri | http://hdl.handle.net/20.500.12627/53223 | |
| dc.description.abstract | The effects of oxalic acid concentration, temperature, stirring rate and particle size on the dissolution rate of synthetically prepared calcium molybdate were investigated. Dissolution of calcium molybdate in oxalic acid solutions takes place as a series - parallel type reaction. In the first reaction step, which proceeds according to the "Langmuir - Hinshelwood Mechanism", calcium aqua oxalato molybdate is formed as a complex chelate intermediate product. In the second reaction step, molybdic acid is formed during the slow hydrolysis of calcium aqua oxalato molybdate, and it reacts rapidly with oxalic acid to form the polymeric hydrogen oxalate dimolybdate chelate as an end product. Activation energies were calculated as 41.4 and 49.9 kJ mol(-1) for the first and zero order reactions. The fractional conversion versus time relationship can be given by the following equation. | |
| dc.language.iso | eng | |
| dc.subject | Mühendislik ve Teknoloji | |
| dc.subject | MALZEME BİLİMİ, KARAKTERİZASYON VE TEST | |
| dc.subject | Metalurji ve Malzeme Mühendisliği | |
| dc.subject | Mühendislik, Bilişim ve Teknoloji (ENG) | |
| dc.subject | Malzeme Bilimi | |
| dc.subject | METALURJİ VE METALURJİ MÜHENDİSLİĞİ | |
| dc.title | A KINETIC INVESTIGATION OF THE DISSOLUTION OF POWELLITE IN OXALIC ACID SOLUTIONS | |
| dc.type | Bildiri | |
| dc.contributor.department | İstanbul Üniversitesi , Mühendislik Fakültesi , Metalurji Ve Malzeme Mühendisliği | |
| dc.contributor.firstauthorID | 138927 | |
