dc.contributor.author | Aydın, Muhammet | |
dc.contributor.author | Apak, Resat | |
dc.contributor.author | Avci, Gulfidan Yenel | |
dc.contributor.author | Cengiz, Salih | |
dc.contributor.author | Anilanmert, Beni | |
dc.date.accessioned | 2021-03-03T09:31:53Z | |
dc.date.available | 2021-03-03T09:31:53Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Anilanmert B., Aydın M., Apak R., Avci G. Y. , Cengiz S., "A Fast Liquid Chromatography Tandem Mass Spectrometric Analysis of PETN (Pentaerythritol Tetranitrate), RDX (3,5-Trinitro-1,3,5-triazacyclohexane) and HMX (Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) in Soil, Utilizing a Simple Ultrasonic-Assisted Extraction with Minimum Solvent", ANALYTICAL SCIENCES, cilt.32, sa.6, ss.611-616, 2016 | |
dc.identifier.issn | 0910-6340 | |
dc.identifier.other | av_1d71b0dd-83a5-4fdb-b1a3-ec98b5dfcc7f | |
dc.identifier.other | vv_1032021 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/24984 | |
dc.identifier.uri | https://doi.org/10.2116/analsci.32.611 | |
dc.description.abstract | Direct analyses of explosives in soil using liquid chromatography tandem mass spectrometry (LC-MS/MS) methods are very limited in the literature and require complex procedures or relatively high amount of solvent. A simple and rapid method was developed for the determination of pentaerythritol tetranitrate (PETN), 3,5-trinitro-1,3,5-triazacyclohexane (RDX) and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), which are among the explosives used in terrorist attacks. A one-step extraction method for 1.00 g soil with 2.00 mL acetonitrile, and a 8-min LC-MS/MS method was developed. The detection limits for PETN, RDX and HMX were 5.2, 8.5 and 3.4 ng/g and quantitation limits were 10.0, 24.5, 6.0 ng/g. The intermediate precisions and Horwitz Ratio's were between 4.10 - 13.26% and 0.24 - 0.98, in order. This method was applied to a model post-blast debris collected from an artificial explosion and real samples collected after a terrorist attack in Istanbul. The method is easy and fast and requires less solvent use than other methods. | |
dc.language.iso | eng | |
dc.subject | Temel Bilimler (SCI) | |
dc.subject | Temel Bilimler | |
dc.subject | KİMYA, ANALİTİK | |
dc.subject | Kimya | |
dc.subject | Analitik Kimya | |
dc.title | A Fast Liquid Chromatography Tandem Mass Spectrometric Analysis of PETN (Pentaerythritol Tetranitrate), RDX (3,5-Trinitro-1,3,5-triazacyclohexane) and HMX (Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) in Soil, Utilizing a Simple Ultrasonic-Assisted Extraction with Minimum Solvent | |
dc.type | Makale | |
dc.relation.journal | ANALYTICAL SCIENCES | |
dc.contributor.department | İstanbul Üniversitesi , , | |
dc.identifier.volume | 32 | |
dc.identifier.issue | 6 | |
dc.identifier.startpage | 611 | |
dc.identifier.endpage | 616 | |
dc.contributor.firstauthorID | 232669 | |