dc.contributor.author | Senol, Aynur | |
dc.contributor.author | Yalcinkaya, Ozlem | |
dc.date.accessioned | 2021-12-10T11:29:26Z | |
dc.date.available | 2021-12-10T11:29:26Z | |
dc.identifier.citation | Senol A., Yalcinkaya O., "Equilibrium study on the reactive extraction of heterocyclic monocarboxylic acids from the aqueous solution using Alamine 300/diluent composite solvent: Optimization and modeling of the solvent effect", ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2021 | |
dc.identifier.issn | 1932-2135 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.other | av_815d881f-b1cf-4994-a841-85a99eed854e | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/171996 | |
dc.identifier.uri | https://doi.org/10.1002/apj.2723 | |
dc.description.abstract | Experiments were conducted to optimize the extraction equilibrium of reactive systems (water + heterocyclic carboxylic acid + Alamine 300/diluent) at T = 298.2 K and P = 101.3 kPa. The uptake capacity of the commercial composite solvent Alamine 300/diluent approximates the order: 2-furoic acid >= alpha-oxo-2-furanacetic acid > tetrahydro-2-furoic acid, and n-heptane < 1,2-dichloroethane < 1-heptanol <= 2-heptanone. Four differentiable models featuring the effects of separation ratio R and synergistic enhancement SE factors are stringently tested to identify global optimization ranges by derivative variation method as follows: 0.2 < R < 0.8 and 4 < SE < 7 for 1-heptanol and 2-heptanone, 1.2 < R < 3.5 and 4 < SE < 6.5 for 1,2-dichloroethane, 2 < R < 80 and 4 < SE < 80 for n-heptane, and Alamine 300 concentration 0.12-0.18 mol dm(-3). Consecutively, the optimum mass transfer stages of a countercurrent extraction are calculated by Kremser-Souders-Brown equation. The equilibrium properties are estimated precisely according to linear solvation energy relation with substantial improvement linear solvation energy relation with substantial improvement (LSER-si), solvation probability relation solvation probability relation (SPR) and Chemodel-modified yielding mean relative errors of 7.0%, 0.08% and 20.4%, respectively. | |
dc.language.iso | eng | |
dc.subject | Chemical Health and Safety | |
dc.subject | Fluid Flow and Transfer Processes | |
dc.subject | Chemical Engineering (miscellaneous) | |
dc.subject | Engineering (miscellaneous) | |
dc.subject | General Chemical Engineering | |
dc.subject | Colloid and Surface Chemistry | |
dc.subject | Catalysis | |
dc.subject | Physical Sciences | |
dc.subject | Kimya Mühendisliği ve Teknolojisi | |
dc.subject | Mühendislik, Bilişim ve Teknoloji (ENG) | |
dc.subject | Mühendislik | |
dc.subject | MÜHENDİSLİK, KİMYASAL | |
dc.subject | General Engineering | |
dc.subject | Mühendislik ve Teknoloji | |
dc.title | Equilibrium study on the reactive extraction of heterocyclic monocarboxylic acids from the aqueous solution using Alamine 300/diluent composite solvent: Optimization and modeling of the solvent effect | |
dc.type | Makale | |
dc.relation.journal | ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING | |
dc.contributor.department | İstanbul Üniversitesi , Mühendislik Fakültesi , Kimya Mühendisliği | |
dc.contributor.firstauthorID | 2770640 | |