dc.contributor.author | Bakiler, M | |
dc.contributor.author | Akyuz, S | |
dc.contributor.author | Maslov, IV | |
dc.date.accessioned | 2021-03-05T19:54:47Z | |
dc.date.available | 2021-03-05T19:54:47Z | |
dc.identifier.citation | Bakiler M., Maslov I., Akyuz S., "Theoretical study of the vibrational spectra of 2-chloropyridine metal complexes II. Calculation and analysis of the IR spectra of Cd- and Ni-2-chloropyridine complexes", JOURNAL OF MOLECULAR STRUCTURE, cilt.476, ss.21-26, 1999 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.other | av_d17dd2e9-2f66-4ef3-8571-70dd708bbb77 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/138466 | |
dc.identifier.uri | https://doi.org/10.1016/s0022-2860(98)00492-x | |
dc.description.abstract | The vibrational IR spectra of a Cd complex of 2-chloropyridine, was calculated on the basis of a parameter set determined in our previous study on the 2-chloropyridine molecule. The Cd-N bond strength was determined by the variation of the force field, and the corresponding force constant is found to be (1.064 mdyne/Angstrom). Calculated IR intensities indicate the presence of some changes in electron distribution of the 2Cl-pyridine molecule in a complex formation, with respect to the free molecule. The distortion of the electro-optical parameters occurs around the N atom. The interpretation of the normal vibrations and IR intensities of the Cd-2Cl-pyridine complex is given. Comparison with the corresponding shifts for the case of the Ni complex of 2Cl-pyridine, ensures that the force field of the free 2Cl-pyridine molecule should be altered in a complex formation, in order to represent experimental data. (C) 1999 Elsevier Science B.V. All rights reserved. | |
dc.language.iso | eng | |
dc.subject | Kimya | |
dc.subject | Temel Bilimler | |
dc.subject | KİMYA, FİZİKSEL | |
dc.subject | Fizikokimya | |
dc.subject | Temel Bilimler (SCI) | |
dc.title | Theoretical study of the vibrational spectra of 2-chloropyridine metal complexes II. Calculation and analysis of the IR spectra of Cd- and Ni-2-chloropyridine complexes | |
dc.type | Makale | |
dc.relation.journal | JOURNAL OF MOLECULAR STRUCTURE | |
dc.contributor.department | , , | |
dc.identifier.volume | 476 | |
dc.identifier.startpage | 21 | |
dc.identifier.endpage | 26 | |
dc.contributor.firstauthorID | 122743 | |