Adsorption behavior of strontium on binary mineral mixtures of Montmorillonite and Kaolinite

Abstract

The adsorption behavior of kaolinite and montmorillonite minerals and their mixtures in respect of Sr ion were studied by means of a batch method using Sr-90 as a radio tracer. The effect of several parameters such as temperature, pH, Sr concentration and supporting electrolyte were investigated. Experimentally measured distribution coefficients showed a good agreement to within 98.5-99.7% with theoretically calculated values. The values of adsorption capacity of adsorbents and mean adsorption energy of adsorption were calculated by fitting the adsorption data to Dubinin-Radushkevich isotherm. The adsorption capacity of clay mixtures decreased as kaolinite fractions increased. The mean adsorption energy values of 8.0-9.5 kJ mol(-1) showed that adsorption was governed by ion exchange. The Freundlich parameters were used to characterize a site distribution function for binary exchange between Sr and Na. (c) 2006 Elsevier Ltd. All rights reserved.